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Adsorption of dye molecules on metallic nanoparticles: Unraveling the origins of the modified spectral absorption

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posted on 2021-12-07, 20:20 authored by Chen, Xiaohan

The enhanced optical response of molecules in the vicinity of metallic nanoparticle is the basis for many surface enhanced spectroscopies and of interest to the field of plasmonics. However, the mechanisms behind the enhancement are still a matter of debate because of the interplay between electromagnetic and chemical effects, which complicates the interpretation of spectral changes. Our ability to measure the surface absorption of dyes from very low coverage to high coverage allows us to identify the con- tribution of each effect (dye-dye interaction and dye-particle interaction) to the spectral modifications. In the course of this investigation, we also measured the adsorption isotherms of dyes in the presence of halide ions, which provides a detailed insight into the adsorption process on silver colloids.

History

Copyright Date

2019-01-01

Date of Award

2019-01-01

Publisher

Te Herenga Waka—Victoria University of Wellington

Rights License

Author Retains Copyright

Degree Discipline

Physics

Degree Grantor

Te Herenga Waka—Victoria University of Wellington

Degree Level

Masters

Degree Name

Master of Science

ANZSRC Type Of Activity code

1 PURE BASIC RESEARCH

Victoria University of Wellington Item Type

Awarded Research Masters Thesis

Language

en_NZ

Victoria University of Wellington School

School of Chemical and Physical Sciences

Advisors

Le Ru, Eric