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The Alkaline solvolysis of allyl bromide in alcohol-water solvents
thesis
posted on 2021-11-12, 10:08 authored by Donald, Valda HilaryThe rate of the alkaline solvolysis of allyl bromide has been measured in various ethanol-water and methanol-water mixtures. This has been found to increase with increase in solvent polarity. An attempt was made to explain this behaviour in terms of partial ionisation of the substrate. It has been suggested that in nucleophilic substitution the individual specific rate constants for attack by alkoxide or hydroxide ions are a better indication of solvent effects than the apparent overall rate constant.
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Copyright Date
1963-01-01Date of Award
1963-01-01Publisher
Te Herenga Waka—Victoria University of WellingtonRights License
Author Retains CopyrightDegree Discipline
ChemistryDegree Grantor
Te Herenga Waka—Victoria University of WellingtonDegree Level
MastersDegree Name
Master of ScienceVictoria University of Wellington Item Type
Awarded Research Masters ThesisLanguage
en_NZVictoria University of Wellington School
School of Chemical and Physical SciencesAdvisors
English, BrianUsage metrics
Keywords
NucleophilicReaction ratesSchool: School of Chemical and Physical Sciences039999 Chemical Sciences not elsewhere classifiedMarsden: 259999 Chemical Sciences not Elsewhere ClassifiedDegree Discipline: ChemistryDegree Level: MastersDegree Name: Master of ScienceChemical Sciences not elsewhere classified
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