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Reactions of Co-Ordinated Ligands: Schiff Base Complexes from Polyamine Complexes and Aliphatic Carbonyls
thesis
posted on 2021-11-05, 02:32 authored by House, Donald AlexanderIn 1954, Curtis(46,47) discovered that tris (ethylenediamine)nickel(II) perchlorate would react with acetone to form three different yellow, diamagnetic perchlorate complexes containing ligands coordinated by amine and azomethine donor groups and Blight(19) extended this reaction to other 1,2-diamine complexes of copper(II) and nickel(II). The object of this work has been:- (i) The synthesis of polyamine complexes of nickel(II) and copper(II)(84). (ii) The investigation of the nature, structure(50) and chemical properties of the products obtained by reaction of some nickel(II) and copper(II) polyamine complexes with acetone(83,85,85). (iii) The extension of the reaction to other aliphatic carbonyl compounds, especially aldehydes.
History
Copyright Date
1963-01-01Date of Award
1963-01-01Publisher
Te Herenga Waka—Victoria University of WellingtonRights License
Author Retains CopyrightDegree Discipline
ChemistryDegree Grantor
Te Herenga Waka—Victoria University of WellingtonDegree Level
DoctoralDegree Name
Doctor of PhilosophyVictoria University of Wellington Item Type
Awarded Doctoral ThesisLanguage
en_NZVictoria University of Wellington School
School of Chemical and Physical SciencesAdvisors
Curtis, Neil FUsage metrics
Keywords
Chemical reactionsSchiff basesLigandsSchool: School of Chemical and Physical Sciences039999 Chemical Sciences not elsewhere classifiedMarsden: 250400 Analytical ChemistryMarsden: 250200 Inorganic ChemistryDegree Discipline: ChemistryDegree Level: DoctoralDegree Name: Doctor of PhilosophyChemical Sciences not elsewhere classified
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