Open Access Te Herenga Waka-Victoria University of Wellington
Browse
thesis_access.pdf (41.76 MB)

Reactions of Co-Ordinated Ligands: Schiff Base Complexes from Polyamine Complexes and Aliphatic Carbonyls

Download (41.76 MB)
thesis
posted on 2021-11-05, 02:32 authored by House, Donald Alexander

In 1954, Curtis(46,47) discovered that tris (ethylenediamine)nickel(II) perchlorate would react with acetone to form three different yellow, diamagnetic perchlorate complexes containing ligands coordinated by amine and azomethine donor groups and Blight(19) extended this reaction to other 1,2-diamine complexes of copper(II) and nickel(II). The object of this work has been:- (i) The synthesis of polyamine complexes of nickel(II) and copper(II)(84). (ii) The investigation of the nature, structure(50) and chemical properties of the products obtained by reaction of some nickel(II) and copper(II) polyamine complexes with acetone(83,85,85). (iii) The extension of the reaction to other aliphatic carbonyl compounds, especially aldehydes.

History

Copyright Date

1963-01-01

Date of Award

1963-01-01

Publisher

Te Herenga Waka—Victoria University of Wellington

Rights License

Author Retains Copyright

Degree Discipline

Chemistry

Degree Grantor

Te Herenga Waka—Victoria University of Wellington

Degree Level

Doctoral

Degree Name

Doctor of Philosophy

Victoria University of Wellington Item Type

Awarded Doctoral Thesis

Language

en_NZ

Victoria University of Wellington School

School of Chemical and Physical Sciences

Advisors

Curtis, Neil F